Methyl halide production and loss rates in sea water from field incubation experiments     

Robert M. Moore   《Marine Chemistry》2006,101(3-4):213-219

Experiments were conducted in the field to determine the non-chemical loss rate of methyl iodide in seawater and to examine production rates of methyl halides. The loss rate of added C13 labelled methyl iodide, present at concentrations similar to those found in seawater, corrected for chemical loss due to reaction with Cl⁻ varied from < 1 to 18% day^− 1, with a mean value of 7%. This rate of loss is much lower than that which was proposed by Bell et al. [Bell, N., Hsu, L., Jacob, D. J., Schultz, M. G., Blake, D. R., Butler, J. H., King, D. B., Lobert, J. M., Maier-Reimer, E., 2002. Methyl iodide: Atmospheric budget and use as a tracer of marine convection in global models, Journal of Geophysical Research-Atmospheres 107(D17), 4340-4351.] to account for the large discrepancies between observed and predicted mid-latitude concentrations of CH₃I based on their global photochemical source model. The suitability of several types of container for seawater incubations was studied and only quartz tubes appeared to be free of experimental artifact. Collapsible polyvinyl fluoride containers showed major production of methyl halides on irradiation with simulated sunlight. Polyethylene containers caused spurious production of methyl iodide at lower rates.  相似文献   

The importance of bioturbation to continental slope sediment structure and benthic processes off Cape Hatteras, North Carolina     

Robert J. Diaz  G. Randy Cutter  Donald C. Rhoads 《Deep Sea Research Part II: Topical Studies in Oceanography》1994,41(4-6)

Even though the continental slope off Cape Hatteras has sediment accumulation rates on the order of 1 cm/year, large areas of soft sediment are intensively reworked by infaunal organisms. Primary sedimentary structures have been completely replaced with biogenic structures. Surface sedimentary structures are dominated by the bioturbational activities of a deep burrowing infauna (to at least 30 cm). The layer actively mixed by the benthos, as evidenced by sediment profile and X-ray images, is estimated to range from 5 to 20 cm, with the residence time for particles within the surface mixed layer ranging from about 4.5 to 18 years. The biological mixing parameter (G) ranges from 0.4 to 5.5, which indicates moderate to strong biological mixing relative to accumulation and strata formation. Bioturbation contributes to the dynamic forces affecting the surface sediments by decreasing compaction of sediment layers and dilating sediment fabrics by sediment mixing, and introducing large water-filled burrows and voids to subsurface sediments. The sediment profile images captured numerous subsurface feeding voids, and worms in the process of making deep burrows, many of which extended below the 5 to 10 cm average depth of the apparent color redoxpotential discontinuity layer. High rates of accumulation of organic-rich sediment lead to high standing stocks of benthos and intensive feeding/burrowing activity that result in organic rich stratagraphic sequences that are thoroughly mixed. Cape Hatteras is a apparent focusing point for the transport of shallow water sediments to the deep sea. Sediments across other areas of the continental slope just 100's of kilometers south of Cape Hatteras are not as thoroughly mixed or biologically active.  相似文献   

A permanent seismic station beneath the Ocean Bottom     

David Harris  Robert K. Cessaro  Fred K. Duennebier  David A. Byrne 《Marine Geophysical Researches》1987,9(1):67-94

The Hawaii Institute of Geophysics began development of the Ocean Subbottom Seisometer (OSS) system in 1978, and OSS systems were installed in four locations between 1979 and 1982. The OSS system is a permanent, deep ocean borehole seismic recording system composed of a borehole sensor package (tool), an electromechanical cable, recorder package, and recovery system. Installed near the bottom of a borehole (drilled by the D/V Glomar Challenger), the tool contains three orthogonal, 4.5-Hz geophones, two orthogonal tilt meters; and a temperature sensor. Signals from these sensors are multiplexed, digitized (with a floating point technique), and telemetered through approximately 10 km of electromechanical cable to a recorder package located near the ocean bottom. Electrical power for the tool is supplied from the recorder package. The digital seismic signals are demultiplexed, converted back to analog form, processed through an automatic gain control (AGC) circuit, and recorded along with a time code on magnetic tape cassettes in the recorder package. Data may be recorded continuously for up to two months in the self-contained recorder package. Data may also be recorded in real time (digital formal) during the installation and subsequent recorder package servicing. The recorder package is connected to a submerged recovery buoy by a length of bouyant polypropylene rope. The anchor on the recovery buoy is released by activating either of the acoustical command releases. The polypropylene rope may also be seized with a grappling hook to effect recovery. The recorder package may be repeatedly serviced as long as the tool remains functionalA wide range of data has been recovered from the OSS system. Recovered analog records include signals from natural seismic sources such as earthquakes (teleseismic and local), man-made seismic sources such as refraction seismic shooting (explosives and air cannons), and nuclear tests. Lengthy continuous recording has permitted analysis of wideband noise levels, and the slowly varying parameters, temperature and tilt.Hawaii Institute of Geophysics Contribution 1909.  相似文献   

The exclusive economic zone : State claims and the LOS convention     

Robert Nadelson 《Marine Policy》1992,16(6)

The rapid acceptance of the exclusive economic (EEZ) concept belies the broad differences among State claims beyond 12 nautical miles, and the wide gulf between State practice and the United Nations Convention on the Law of the Sea (LOS Convention). This paper first examines the areas of contention between State practice and the LOS Convention. These differences are characterized and the author concludes that the EEZ regime within the Convention does not address the specific individual and regional needs of States that have resulted in the wide discrepancy among State claims. The author suggests a global authority under which the jurisdictional line would be redrawn along the practical level of coastal State to vessel, rather than the political plane of coastal State to flag State.  相似文献   

Fluctuation of transports and Sea level in the western boundary region of the tropical Pacific Ocean     

T. Robert Kendall 《Journal of Oceanography》1989,45(4):279-287

Large fluctuation in transport of the Equatorial Countercurrent flowing eastward from the western boundary is not the direct result of fluctuation in transport of the North Equatorial Current, but rather relates to fluctuation of sea level anomaly in the Philippine Sea.  相似文献   

Reducing fishing vessel fuel consumption and NO_X emissions     

Robert Latorre   《Ocean Engineering》2001,28(6)

There is a growing concern with the impact of marine operations on the environment. This requires reducing fuel consumption and vessel pollution during operation. On-board computers and satellite communications will enable the operator to reduce fuel consumption and NO_X emissions during vessel operations.This paper presents the results of a study on this problem and how such an on-board system could be implemented to reduce fuel consumption and engine NO_X emissions.  相似文献   

Determination of phospholipid fatty acid structures and stable carbon isotope compositions of deep-sea sediments of the Northwest Pacific, ODP site 1179   总被引：1，自引：0，他引：1  

Christopher T. Mills  Robert F. Dias  Dennis Graham  Kevin W. Mandernack   《Marine Chemistry》2006,98(2-4):197-209

Sediment samples ranging from 0.05 to 278 m below sea floor (mbsf) at a Northwest Pacific deep-water (5564 mbsl) site (ODP Leg 191, Site 1179) were analyzed for phospholipid fatty acids (PLFAs). Total PLFA concentrations decreased by a factor of three over the first meter of sediment and then decreased at a slower rate to approximately 30 mbsf. The sharp decrease over the first meter corresponds to the depth of nitrate and Mn(IV) reduction as indicated by pore water chemistry. PLFA-based cell numbers at site 1179 had a similar depth profile as that for Acridine orange direct cell counts previously made on ODP site 1149 sediments which have a similar water depth and lithology. The mole percentage of straight chain saturated PLFAs increases with depth, with a large shift between the 0.95 and 3.95 mbsf samples. PLFA stable carbon isotope ratios were determined for sediments from 0.05 to 4.53 mbsf and showed a general trend toward more depleted δ¹³C values with depth. Both of these observations may indicate a shift in the bacterial community with depth across the different redox zones inferred from pore water chemistry data. The PLFA 10me16:0, which has been attributed to the bacterial genera Desulfobacter in many marine sediments, showed the greatest isotopic depletion, decreasing from − 20 to − 35‰ over the first meter of sediment. Pore water chemistry suggested that sulfate reduction was absent or minimal over this same sediment interval. However, 10me16:0 has been shown to be produced by recently discovered anaerobic ammonium oxidizing (anammox) bacteria which are known chemoautotrophs. The increasing depletion in δ¹³C of 10me16:0 with the unusually lower concentration of ammonium and linear decrease of nitrate concentration is consistent with a scenario of anammox bacteria mediating the oxidation of ammonium via nitrite, an intermediate of nitrate reduction.  相似文献   

JGOFS studies in the equatorial Pacific     

James W. Murray  Robert Leborgnelt  Yves Dandonneau 《Deep Sea Research Part II: Topical Studies in Oceanography》1997,44(9-10)

This special issue is the third and final volume containing results from the JGOFS Process Study in the equatorial Pacific. Most of the Study in the equational Pacific. Most of the contributions evolved either from the US JGOFS workshop in 1994 on the equatorial Pacific in Scottsdale, AZ or from the NATO Advanced Research Workshop on the Carbon Cycle of the Equatorial Pacific in 1995 in Noumea, New Caledonia.  相似文献   

Hydrothermal Vent Geology and Biology at Earth’s Fastest Spreading Rates     

Richard N. Hey  Gary J. Massoth  Robert C. Vrijenhoek  Peter A. Rona  John Lupton  David A. Butterfield 《Marine Geophysical Researches》2006,27(2):137-153

Earth’s fastest present seafloor spreading occurs along the East Pacific Rise near 31°–32° S. Two of the major hydrothermal plume areas discovered during a 1998 multidisciplinary geophysical/hydrothermal investigation of these mid-ocean ridge axes were explored during a 1999 Alvin expedition. Both occur in recently eruptive areas where shallow collapse structures mark the neovolcanic axis. The 31° S vent area occurs in a broad linear zone of collapses and fractures coalescing into an axial summit trough. The 32° S vent area has been volcanically repaved by a more recent eruption, with non-linear collapses that have not yet coalesced. Both sites occur in highly inflated areas, near local inflation peaks, which is the best segment-scale predictor of hydrothermal activity at these superfast spreading rates (150 mm/yr).  相似文献   

Prolonged Magmatic and Tectonic Development of the Caribbean Igneous Province Revealed by a Diving Submersible Survey     

Mauffret  Alain  Leroy  Sylvie  Vila  Jean-Marie  Hallot  Erwan  Mercier de Lépinay  Bernard  Duncan  Robert A. 《Marine Geophysical Researches》2001,22(1):17-45

Using the diving submersible survey NAUTICA we investigated the central part of the Caribbean large igneous province (CLIP) to observe and sample internal portions of this proposed oceanic plateau. Most of the samples are gabbroic and doleritic rocks; basalts are scarce. Radiometric dating by ⁴⁰Ar/³⁹Ar incremental heating experiments indicate that the intrusive rocks are Campanian in age (81–75 Ma). In some places these intrusive rocks underlie older Santonian (85–83 Ma) extrusive basaltic rocks, suggesting that the Campanian rocks represent a sill injection and an underplating episode. Results of the diving program supplemented by information from ODP and DSDP drilling sites document a 20 m.y. period (94–75 Ma) of igneous activity in the submerged portion of the Caribbean large igneous province (CLIP). In the northern part of the Beata Ridge late Campanian and/or post Campanian uplift is documented by prominent Maastrichtian (71–65 Ma) erosion and the establishment of a Paleocene-middle Eocene (65–49 Ma) carbonate platform. During and after the uplift an extensional period is indicated by seismic images and the subsidence (3 km depth) of the carbonate platform. Paleocene ages (55–56 Ma) determined on some volcanic samples are attributed to localised decompression mantle melting that accompanied the extension. We document a prolonged period of magmatic and tectonic events that do not fit with the current models of short-lived plateau formation during mantle plume initiation but shares many similarities with the constructional histories of other oceanic large igneous provinces.  相似文献